Type 439 is a titanium stabilized, 18 percent chromium alloy that may be used in many oxidizing environments where type 304 is considered adequate in terms of general corrosion resistance but is. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. The effect of alloying elements and how these elements affect the electrochemical response in 50% naoh environments can be assessed, by comparing individual alloy responses. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap.
Hence the tendency for stress corrosion cracking of the plain 304 or 316 stainless steels in solution annealed condition is not considered to be different from its low carbon varieties. There is an additional risk of stress corrosion cracking scc at higher temperatures. Type 321 stainless steel offers higher creep and stress rupture properties than type 304 and, particularly, type 304l which might also be considered for exposures where sensitization and intergranular corrosion are concerns. Scc in a 316 stainless steel chemical processing piping system. Summary of available data for estimating chlorideinduced scc. The combination of the high molybdenum and chromium content, along with the. The interaction of corrosion fatigue and stresscorrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stress corrosion cracking resistance is superior to the austenitic grades of stainless steel. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Type 304 stainless steel an overview sciencedirect topics. Analysis of a 25yearold 304 stainless steel handhole gasket from a. Pitting and crevice corrosion can occur in environments containing chlorides. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Pdf chloride induced stress corrosion cracking of type 304 and. What forms of corrosion can occur in stainless steels. Effect of halogens and inhibitors on the external stress.
Causticinduced scc can occur in breweries where concentrated caustic solutions. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular. It has excellent forming and welding characteristics.
Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Aisi 304 grade stainless steel uns s30400 aisi 304 stainless steel uns s30400 is the most commonly used material in stainless steels, and is usually purchased in an annealed or cold worked. Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Austenitic stainless steels crni types 304, 304l, 321, and similar and crnimo types 316, 316l, 316 ti, and similar are susceptible to atmosphericallyinduced stress corrosion cracking.
The datasheet and specification are summarized in the following tables including. Type 321 stainless steel s also advantageous for high temperature service because of its good mechanical properties. Film and ph effects in the stress corrosion cracking of. Pdf chloride stress corrosion cracking scc of type 304 and.
Ss304 grade aisi 304 stainless steel properties, composition. Stabilised grades for heavy section welding and high temperature applications. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Stress corrosion cracking of an austenitic stainless steel in. Conditions which cause stress corrosion cracking are. Chloride stress corrosion cracking ssina specialty steel. Stress corrosion cracking of sensitized stainless steel type 304 in. C 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission.
Detecting and imaging stress corrosion cracking in. Ak steel 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Corrosion and corrosion properties of stainless steels. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Below 80 degc they can be considered resistant to any concentration of sodium hydroxide, up to the. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Coldworked 304 stainless steels ss are known to be susceptible to stress corrosion cracking scc. For more information, please check 304 vs 316 stainless steel. Stresscorrosion cracking of sensitized type 304 stainless. Pdf chloride induced stress corrosion cracking of type 304. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
Figure 3 shows two microstructures of type 304 stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework. This results because of their similarity in nickel content. Influence of high temperature on corrosion behavior of 304. Improved resistance to pitting corrosion in chloride environments. The presence of 23 wt% molybdenum in the alloy makes the passive film stronger kain et al. Stress corrosion cracking scc is a common issue with many specialty alloys. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
Design guidelines for the selection and use of stainless steel nidl distributed by. Sensor requirements for detection and characterization of. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. A key question is the nature of irradiationassisted intergranular cracking at very high dose, i. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. The low carbon version, 304l, may be required for full corrosion resistance when thicker sections are welded.
Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Most notably, pitting and cracking in this instance had initiated andor. Stainless steel 304 has excellent corrosion resistance in a wide variety of environments and when in contact with different corrosive media. Stainless steel 304l an overview sciencedirect topics. Stress corrosion cracking of an austenitic stainless steel.
It is also referred to as 188 stainless steel, a2 stainless steel as per the iso 3506, or 304s15 as per the. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay. Stress corrosion cracking of sensitized type 304 stainless. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Pitting resistance is also superior in comparison to types 304 and 316. Preventing stress corrosion cracking of austenitic stainless steels in. To fill this need, the committee of stainless steel producers initially prepared this booklet. Stainless steel grade 304 cs 304 304l technical data. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367. Effects of fluoride and other halogen ions on the external. This study employs atomprobe tomography apt for local chemical analysis of the oxides formed. The corrosion data in this section is mainly based on the results of general corrosion laboratory tests, which are not strictly comparable with actual service conditions. The multiple crevice assembly mca method described in astm g4829 and previous studies, was adopted to study the crevice corrosion and stress corrosion cracking behavior of type 30409a.
Slow strain rate tests ssrts were conducted on 304 steel in. The type 302, 304, 304l and 305 alloys are the most susceptible of the austenitic stainless steels to stress corrosion cracking in halides because of their relatively low nickel content. Reference is often made to stainless steel in the singular sense as if it were one material. The effects of titanium ion implantation on the stress corrosion cracking scc behaviour of 304 austenitic stainless steel were studied. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Summary of available data for estimating chlorideinduced scc crack growth rates for. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Characterization of intergranular stress corrosion. The saeansi 304 aisi 304 is the most commonly available and used type of stainless steel. The general level of corrosion resistance of ak steel 2205 duplex is superior to types 304 and 316 in most cases.
The chloride ion cl is the most common of these and is found in everyday materials such as salt and. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Therefore, standard grades such as 304304l and 316316l are very susceptible to this mode of attack. Stress corrosion cracking scc of duplex stainless steel. Deterioration by clscc can lead to failures that have the potential to release. The lower carbon content minimizes chromium carbide precipitation due to welding and its susceptibility to intergranular corrosion. Chloride stress corrosion cracking in austenitic stainless. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Film and ph effects in the stress corrosion cracking of type.
Chloride stress corrosion cracking in austenitic stainless steel. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic. It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. Type 304 stainless steel is highly susceptible to scc in chloride solution as demonstrated by the. Atmospheric stress corrosion cracking of stainless steel. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries.
Grade 304 is the most commonly used stainless steel. Stress corrosion cracking susceptibility of 304l substrate. Pdf stress corrosion cracking of stainless steel components in. The author explains this by relating it to the austenitic steel properties, such as coefficient of thermal expansion, thermal conductivity and elevated flow stress, or with the simpler hardnessstrength distribution observed in stainless steels that are welded in an annealed condition when compared to fsw highstrength aluminium alloys. The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. Chloride stress corrosion cracking inspectioneering. It is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. From the wealth of research data on rapid causticscc of stainless steel, it is clear. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Stainless steels stainless 304 properties, fabrication. This paper presents a fusion welding process that was developed for snf canister repair.
Corrosion behaviour of type 316l stainless steel in hot. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Abstract intergranular stress corrosion cracking igscc of austenitic stainless steels and nickel base alloys continues to be a major problem in light water reactors.
Stainless steel grade 304 is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. Formability formability of ak steel 2205 duplex is better than. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Our data bases and mechanistic understanding of the degradation of such highly irradiated components, however, are not well established. Figure 1 shows data on the susceptibility of type 304 stainless steel to stress corrosion cracking under certain conditions. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This mode of attack is termed stress corrosion cracking scc. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay between 1.
This work explores the fate of the coupling current generated during stress corrosion cracking of sensitized type 304 stainless steel 304ss in thiosulfate solution at ambient temperature. Written especially for design engineers, it presents an overview of a broad range of stainless steels both standard and proprietary their compositions. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Alloy c276 nickel alloy plate has excellent corrosion resistance in both oxidizing and reducing environments. Autoclave experiments on a set of samples withwithout coldwork prior to oxidation, and withwithout stress applied during oxidation, were carried out under simulated pressurised water reactor. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Grade 304 stainless steel is the most versatile and the most widely used of all stainless steels. Pitting or crevice corrosion can occur on most stainless steel grades. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Stainless steel datasheets revised november 2011 page 1 of 1 au austenitic stainless steels 301, 301l, 301ln high strength for roll formed structural components 302hq low. Both 304 and 316 stainless steel types are resistant to a wide range of concentration and temperature. Although most research has been done on the mechanism of igscc, little is known. Nuregcr7030, atmospheric stress corrosion cracking.
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